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When light passes
from air into water (or glass), or water into air, different colors are
refracted (bent) a different amount. Red is refracted the least, and violet the
most. And so, the colors are separated into a spectrum, or rainbow. When
raindrops are in the air, most light is either reflected off of the drops or
goes right through them. If the light enters at certain angles, the light
enters the drop, is reflected inside, and then exits the drop. Entering and
exiting the drop, the colors are separated. You see red light come from a
raindrop because that drop is at just the correct angle (about 42 degrees)
between your eye and the sun so that the red light coming from the sun is
refracted, reflected, and refracted again right into your eye. Blue light comes
from another raindrop at a slightly different angle. All the raindrops that are
at a certain angle between your eye the sun form a circle in the sky. That is
why the rainbow is a circle.
See How Far Away Is A Rainbow?